How to Solve the Problem of High-Alumina Refractory Mortar Drying too Quickly on the Construction Site?

Refractory mortar, also known as refractory clay or fire mortar, is a material used in furnace construction to fill the joints between refractory bricks, bonding them together and providing the masonry with a certain degree of integrity, strength, and airtightness. Therefore, the use of refractory mortar has a significant impact on the quality of the masonry, the heat loss of the electric furnace, and the furnace shell temperature.

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    How to solve the problem of high-alumina refractory mortar drying too quickly on the construction site?

    If high-alumina refractory mortar dries too quickly on the construction site, it will prevent the refractory bricks from forming a bond, affecting the construction progress. There are several solutions.

    • First, check the ambient temperature at the construction site. Is the high-alumina refractory mortar not watered enough or not mixed evenly? If the mortar is too thick or has poor water retention, it will dry too quickly. Therefore, if the site temperature is too high, the mixed high-alumina refractory mortar should be covered with a damp cloth and not left exposed.
    • Secondly, if too much high-alumina refractory mortar is mixed in a single batch and exposed for too long, the surface will form a skin and lose water, also causing it to dry too quickly and affecting the construction progress. It is best to mix small batches at a time, using them within approximately 30 minutes.
    • If the temperature and mixing are normal, 0.2-0.5% hydroxypropyl methylcellulose (HPMC) can be added to slow down water loss. Alternatively, 0.5-1% dextrin or methylcellulose can be added to increase viscosity and delay drying, allowing sufficient time for refractory bricklaying. However, excessive binder should be strictly avoided to prevent decreased strength and cracking at the joints later on.
    • If the construction site is in a mountainous area with inconvenient transportation, or if the supplier adds excessively long transport times for the binder, add approximately 20% drinking water when mixing the high-alumina refractory mortar, let it stand for 2-3 minutes, and then add the remaining 5-10%. A small amount of household detergent can be added during mixing to increase the viscosity of the high-alumina refractory mortar and prevent delays in construction. (This method is only applicable when the construction site is in a remote mountainous area with inconvenient transportation.)

    In summary, the above are all remedial measures. Ideally, the manufacturer should conduct proper process proportioning and testing during production to ensure that the high-alumina refractory mortar powder is above 180 mesh, has strong adhesion, and does not delay on-site construction time.

    Can high-alumina refractory mortar still be used after long storage?

    High-alumina refractory mortar is a jointing material. If it has been stored for a long time, its usability needs to be assessed. Individually packaged binders that have been stored for more than 6 months cannot be used and must be replaced. If there is no binder, you can judge by smell; if there is no odor, you can re-mix the binder and use it. If the binder was added directly and stored for more than 6 months, a test can be conducted. If it can bond two refractory bricks, it can be used; otherwise, add a reasonable proportion of binder and test again. If successful, it can be used.

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      If there is no individually packaged binder, you can take a small amount and smell it. If there is an odor, the binder was already added to the refractory powder during production. If there is no odor, it proves that the binder was not added. If they were not mixed together, you can re-mix the binder and use it.

      If the binder was added directly during the production of the high-alumina refractory mortar and the storage time has exceeded 6 months, a simple test should be conducted on-site. Weigh 1 kg of refractory powder, add 20-25% drinking water, and stir the refractory powder into a slurry. Take two refractory bricks of the same material, apply a portion of the refractory mortar to one brick, smooth it out, and then place the second brick on top. Rub the two bricks back and forth about fifteen times. If the two bricks stick together, the high-alumina refractory mortar is still usable.

      If the high-alumina refractory mortar cannot bond the two bricks, add some binder in a proper ratio. Then conduct another on-site test using the above method. If the bricks bond together, it is ready for use.

      The binder in high-alumina refractory mortar is for promoting adhesion of the slurry. After being baked at high temperatures, the binder essentially disappears. Therefore, the use of high-alumina refractory mortar that has been stored for a long time depends on its condition.

      Requirements and Selection of Refractory Mortar for Refractory Brick Laying

      Requirements for refractory mortar when laying refractory bricks:

      (1) It should be able to be mixed with water to a certain consistency, filling uneven parts of the brick without causing cracks.

      (2) It should have properties similar to the brick body (e.g., refractoriness, softening temperature under load).

      (3) It should have good airtightness after drying and at high temperatures.

      (4) It should have certain mechanical strength and good airtightness.

      Selection of Refractory Mortar for Laying Refractory Bricks

      Commonly used refractory mortars include clay-based, high-alumina, silica-based, and magnesia-based refractory mortars. Clay-based refractory mortar should be used when laying clay refractory bricks. Clay-based refractory mortar is composed of clay clinker and binding clay.

      High-alumina refractory mortar should be used when laying high-alumina bricks. When laying high-alumina bricks containing 60%-70% Al₂O₃, the refractory mortar used consists of 75%-85% calcined alumina and 10%-20% raw clay. When laying high-alumina bricks containing 48%-55% Al₂O₃, high-refractory clay-based refractory mortar can also be used.

      When laying silica bricks, silica refractory mortar with a SiO₂ content of 90%-93% should be used. Its particle size distribution should be: no more than 3% of particles remaining on a 1.0 mm sieve, and no less than 80% of particles passing through a 0.20 mm sieve.

      When laying magnesia bricks, magnesia refractory mortar should be used. Its magnesium oxide content should be no less than 78%, its silicon oxide content no less than 6%, and its caustic soda content no more than 2%. The particle size distribution of the magnesia refractory mortar is: 100% smaller than 1 mm; no less than 97% smaller than 0.5 mm; and no less than 50% smaller than 0.125 mm.

      Fine-grained refractory mortar is typically used for building electric furnaces.

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        Formulation and Properties of Corundum and High-Alumina Refractory Mortar

        Refractory mortar is an unshaped refractory material composed of powdered materials and binders, used for preparing slurries. The powdered materials are made from fully sintered clinker (such as high-alumina clinker, calcined silica, magnesia, etc.) or other volume-stable refractory raw materials (such as silica, wax stone).

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        The powder used to make refractory mortar can be fully sintered clinker and other volume-stable refractory raw materials. The particle size of the powder depends on the application requirements, with a generally limited particle size of less than 1mm, and sometimes less than 0.5mm or even finer. A reasonable particle composition has a significant impact on ensuring the mortar’s workability, as do the binders and admixtures. Ordinary refractory mortars use bonded clay as the binder. However, chemical binders are increasingly widely used. Adding various admixtures to refractory mortar can improve its workability. For example, adding water-retaining agents to extend the water loss time and ensure construction quality; adding plasticizers, even in small amounts, can increase the mortar’s plasticity; adding dispersants to improve the mortar’s fluidity, etc.

        Refractory mortars can be classified into hydraulic, thermohardening, and air-hardening refractory mortars based on their binder setting and hardening characteristics. Hydraulic refractory mortars use cement as a binder and can be used at room temperature or in places where they may frequently come into contact with water or moisture. Thermosetting refractory mortars are commonly made with thermosetting binders such as phosphoric acid or phosphates. After hardening, these mortars exhibit high strength at various temperatures, low shrinkage, tight joints, and strong erosion resistance. Air-hardening refractory mortars commonly use air-hardening binders such as sodium silicate. These mortars ensure tight joints in masonry.

        Depending on the material of the refractory powder used, commonly used refractory mortars can be classified as: clay-based, silica-based, high-alumina-based, magnesia-based, and insulating. Refractory mortar is mainly used as a contact and surface coating for refractory brick masonry. When used as a jointing material, its quality has a significant impact on the lifespan of the masonry. It can adjust dimensional errors and irregular shapes of bricks, making the masonry neat and load-bearing. It also helps the masonry form a strong and tight whole, resisting external damage and preventing the infiltration of molten metal.

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          Corundum Refractory Mortar

          The formulation of corundum refractory mortar mainly uses sintered corundum clinker or fused alumina with a diameter of 0.5-0.63 mm and finer. Fused alumina with a diameter of 5-7 μm or industrial alumina with a diameter of less than 5 μm is used as a binder. To ensure the shrinkage of the refractory clay during air and firing, the industrial alumina content in the formulation should not exceed 15%-20%, while the content of ultrafine fused alumina powder should reach 40%-50%. 10% of the refractory mortar is introduced with orthophosphoric acid (density 1.72 g/cm³).

          Using corundum clinker and introducing less than 0.1% fermented alcohol waste liquid can improve the plasticity of the slurry and reduce its water content. This refractory mortar has a normal moisture content of less than 19%, a weight loss of 1.8% when heated to 110°C, and an apparent porosity of 26%. As shown in Table 1, the refractory clay has sufficient shear bond strength after firing at 1000-1500°C.

          Properties of Corundum Refractory Mortar
          Properties of Corundum Refractory Mortar

          Note: Component 1 is a refractory mortar primarily composed of sintered corundum, with particles smaller than 0.5 mm, 10% phosphoric acid, and 0.1% fermented alcohol waste liquid. Component 2 is a refractory mortar primarily composed of industrial alumina, with particles smaller than 30 μm, 5.5% polyphosphoric acid, and 0.1% fermented alcohol waste liquid. Component 3 is a refractory mortar primarily composed of light-burned alumina, bonded with sodium pyrophosphate. Component 4 is a refractory mortar primarily composed of high-alumina clinker, 10% clay, 0.1% fermented alcohol waste liquid, and 0.15% sodium carbonate.

          According to Table 1, the shear bond strength of the refractory mortar is related to the final porosity; as porosity increases, the shear bond strength tends to decrease. To maintain the uniformity of the moisture content of the corundum refractory mortar at 2.5%, some dust needs to be removed, and 2.5% CaCl2 needs to be introduced. This increases the moisture content of the slurry to 24%–27%, without reducing the cohesive strength between the refractory mortar and the corundum refractory material. The shear bond strength after firing at 1000°C is 1.4–2.0 MPa, and reaches 10 MPa after firing at 1500°C.

          Phosphate-bonded corundum refractory mortar can withstand 40 cycles of repeated water exchange at 1300°C without cracking. Corundum refractory mortar containing approximately 96% alumina has a refractoriness of 2000°C. Reducing the alumina content in the refractory mortar to 90%–91% slightly decreases the refractoriness, and the deformation initiation temperature under a 0.2 MPa load drops to 1580°C.

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            High-Alumina Refractory Mortar

            The technical properties of high-alumina refractory mortar are shown in Table 2.

            Properties of High-Alumina Refractory Mortar
            Table 2: Properties of High-Alumina Refractory Mortar

            Storage and Usage Principles of High-Alumina Mortar

            High-alumina mortar is the jointing material for high-alumina refractory bricks, mainly used for bonding bricks. Its storage time affects its performance, and its continued usability can be determined.

            Judging the Storage Condition of the Binder

            1. Check the Binder Packaging

            First, check if there is a separately packaged binder in the high-alumina refractory mortar. If there is a separately packaged binder, and the storage time exceeds 6 months, it cannot be used and needs to be replaced.

            If there is no separately packaged binder, take a small amount of refractory mortar and smell it. If there is an odor, it means that the binder was added to the refractory powder during production; if there is no odor, it means that the binder was not added.

            1. Advantages of No Added Binder

            High-alumina mortar without added binder is in its optimal state. It can be remixed with binder and used again, thus ensuring its bonding performance.

            Judgment of Refractory Mortar with Added Binder

            If the high-alumina refractory mortar has had a binder added directly during production and has been stored for more than 6 months, the following test is required to determine its usability:

            1. Test Preparation

            Weigh 1 kg of refractory powder, add 20%-25% drinking water, and stir to form a slurry. Prepare two refractory bricks of the same material.

            1. Test Procedure

            Take a portion of the refractory mortar and evenly spread it on one refractory brick, smooth it out, and place the second refractory brick on top. Rub the two refractory bricks back and forth approximately 15 times.

            1. Result Judgment

            If the two refractory bricks can bond together, the high-alumina refractory mortar is still usable. If the refractory bricks cannot bond, add an appropriate amount of binder in a reasonable proportion and repeat the above test. If the refractory bricks bond successfully, they can be put into use.

            Summary of High-Alumina Refractory Mortar Usage

            The binder in high-alumina refractory mortar primarily promotes the adhesion of the mortar. However, the binder will disappear after high-temperature baking. Therefore, high-alumina mortar that has been stored for a long time needs to be assessed for its continued usability using the methods described above. By checking the storage condition of the binder and conducting simple tests, the feasibility of using high-alumina refractory mortar can be effectively determined, avoiding the impact of material issues on the bonding effect and construction quality of refractory bricks.

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