Basic refractory castables represent a significant advancement and evolution in refractory castable technology. Currently, the range of basic refractory castables includes magnesia, magnesia-chrome (MgO-Spinel), magnesia-alumina (MgO-Spinel), magnesia-zirconia, magnesia-alumina-zirconia (MgO-Spinel-ZrO₂), magnesia-alumina-titania [MgO-Spinel(Ti)], and MgO-CaO castables, among others. Typically, the formulations for basic refractory castables are designed with an ultra-low cement bond (utilizing ultrafine powders, with CAC serving as a setting accelerator) or a cement-free bond (utilizing ultrafine powders); designs incorporating a low-cement bond (CAC + ultrafine powders) are comparatively rare.
As we have previously discussed, there are several major challenges regarding basic refractory castables that require resolution:
- Ensuring sufficient working time.
- Preventing the hydration of fine basic powders during the drying process.
- Maintaining excellent volume stability under conditions involving multiple thermal cycles.
- Minimizing slag penetration during operational use.
- Preventing structural spalling when in contact with basic ferrites (iron-oxide-bearing slags).
How to Improve the Slag Penetration Resistance of Basic Refractory Castables?
Apart from issues related to hydration, another significant challenge facing basic refractory castables is their low resistance to slag penetration.
To address this, studies have investigated the incorporation of additives such as SiO₂, Al₂O₃, Cr₂O₃, and ZrO₂·SiO₂ to enhance the material’s resistance to slag penetration. The results indicated that ZrO₂·SiO₂ offered the highest resistance to slag penetration; however, its use was accompanied by a significant issue: severe corrosion. Consequently, researchers explored the combined addition of Al₂O₃ and TiO₂ to MgO-rich alkali refractory castables. This approach aims to generate a [MgO-Spinel(Ti)ss] material system, utilizing a magnesium-titanium spinel solid solution [Spinel(Ti)ss] as the bonding phase. Upon firing, materials of this type fall under the category of spinel-bonded MgO-spinel refractory castables.
Many researchers have observed a crucial fact: the addition of fine spinel powder to refractory castables helps to improve their resistance to slag penetration. Furthermore, it has been found that the finer and more uniform the added spinel particles are, the more effectively they limit slag penetration. However, even extremely fine pre-synthesized spinel powders are significantly larger than the spinel formed via *in-situ* reactions. Refractory castables containing pre-synthesized fine spinel powder offer only limited protection against slag penetration into the matrix, whereas *in-situ* formed spinel effectively restricts such penetration. This conclusion has been consistently validated in practical applications involving basic refractory castables.
Additionally, controlling the penetration of slag into the matrix of basic refractory castables can be achieved by increasing the slag’s viscosity; both fine SiO₂ and Al₂O₃ powders are effective in increasing slag viscosity.
Given the reactivity of basic refractory castables with molten metals and their susceptibility to corrosion by basic slags, it is necessary to limit the amount of added SiO₂. This is particularly true for basic refractory castables utilizing ultra-fine SiO₂ (uf-SiO₂) as a binder; while the use of uf-SiO₂ reduces slag penetration, it simultaneously increases the material’s susceptibility to corrosion. In such instances, the combined use of ultra-fine Al₂O₃ (uf-Al₂O₃) can serve to strike a balance between the material’s corrosion resistance and its resistance to slag penetration. This figure indicates that when the addition of fused SiO₂ (medium-sized particles) is 4% and the addition of uf-Al₂O₃ is no less than 5%, the magnesia refractory castable exhibits superior erosion resistance and penetration resistance.

Magnesia-Cement Refractory Castables
Magnesia cements primarily include periclase cement and periclase-spinel cement; these are produced by finely grinding highly recrystallized sintered magnesia.
Setting and Hardening Mechanism of Magnesia-Cement Refractory Castables
The mechanism responsible for their setting and hardening is primarily the hydration reaction of magnesium oxide and the crystallization of magnesium hydroxide.
However, the hydration rate of periclase cement is relatively slow; therefore, admixtures—such as magnesium chloride, magnesium sulfate, and magnesium nitrate—should be added to accelerate the hydration and crystallization processes. It is well known that magnesium hydroxide exhibits very low solubility in water, making it difficult for its colloidal gel to crystallize into large particles.
Upon the addition of these admixtures, the boiling point of the mixing water is elevated, and the solubility of magnesium hydroxide is increased, thereby accelerating the crystallization and growth of the magnesium hydroxide gel. These acicular (needle-like) brucite crystals intergrow, imparting strength to the magnesia-cement refractory castable.
Magnesium chloride admixtures generally yield superior results compared to other admixtures, such as magnesium sulfate. This is because magnesium chloride admixtures also facilitate the formation of magnesium oxychloride, which gradually crystallizes and further promotes the setting and hardening of the cement.
Enhancing the Intermediate-Temperature Strength of Periclase-Cement Refractory Castables
The mix design for magnesia-cement-bonded refractory castables typically consists of refractory aggregates (specifically metallurgical magnesia aggregates and chrome slag), cement, and iron powder. A solution containing magnesium chloride and magnesium sulfate is added as the mixing liquid, while the iron powder functions as a mineralizer or sintering aid.
The maximum service temperature for this class of refractory castables is 1600°C. Periclase-cement refractory castables exhibit high strength after drying. However, at temperatures around 400°C, the strength begins to decline due to the thermal decomposition of magnesium hydroxide. As the heating temperature increases further, the microstructure becomes more porous, and the strength continues to diminish. When the temperature reaches the 1000–1200°C range—prior to the onset of sintering—the strength drops to its lowest point, ranging from a mere 2.5 to 9.3 MPa. Once the temperature exceeds 1200°C, the strength recovers slightly due to the recrystallization of magnesium oxide. At approximately 1400°C, solid-phase reactions commence, resulting in an increase in strength to approximately 25% of the dried strength. The addition of iron powder and chrome slag promotes the sintering of periclase, thereby enhancing the medium-temperature strength.

















