Applications of High-Strength Wear-Resistant Al2O3-SiC-C Castables

High-strength wear-resistant castables are suitable for use in areas of industrial kilns subject to severe abrasion. Compared to standard refractory castables, they possess higher density and superior wear resistance; furthermore, they are capable of withstanding impact forces at high temperatures and exhibiting strong shear resistance under heavy structural loads.

The defining characteristics of wear-resistant castables are their compressive strength, flexural strength, and abrasion resistance. These properties are directly linked to the specific process formulation and the raw materials utilized. The raw materials used in wear-resistant refractories typically feature a high alumina content and high bulk density; additionally, the aggregate particles within the process mix are generally larger than those found in standard refractory formulations. Incorporating a specific proportion of silicon carbide into the mix further enhances the castable’s flexural strength and wear resistance.

High-Strength Wear-Resistant Castables Refractory
High-Strength Wear-Resistant Castables Refractory

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    Performance Characteristics of Wear-Resistant Castables

    When a suitable proportion of steel fibers is added to wear-resistant castables, their tensile strength is significantly increased, resulting in improved operational performance. During production, the addition of heat-resistant stainless steel fibers to the aggregate and powder mixture helps prevent thermal expansion-induced stresses at high temperatures and enables the material to withstand the thermal gradient stresses generated during furnace start-up and shut-down cycles. Thanks to the inclusion of steel fibers, the cast furnace lining exhibits enhanced structural integrity and tensile bonding strength. If nickel-plated stainless steel fibers are utilized, the material demonstrates even greater high-temperature stability, as well as enhanced resistance to oxidation and thermal fatigue.

    High-strength, wear-resistant castables are available in various grades, distinguished by differing bulk densities and performance specifications. The specific grade selected for a given application is determined by the operating temperature and the atmospheric conditions within the furnace. Regardless of the specific quality grade, however, superior wear resistance remains a fundamental characteristic inherent to every variety of this castable material.

    Where Are Wear-Resistant Castables Most Effectively Applied?

    High-strength, wear-resistant castables are ideally suited for use in the front and rear arch walls of various industrial boilers, as well as in the furnace linings of waste incinerators. Additionally, composite-type wear-resistant castables are frequently employed in areas such as electric furnace roofs, heating furnace hearths, cement rotary kiln mouths, and material-retaining rings.

    Al2O3-SiC-C Castable Refractory
    Al2O3-SiC-C Refractory Castable

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      Properties and Applications of Al2O3-SiC-C Refractory Castables

      Alumina-Silicon Carbide-Carbon (Al2O3-SiC-C) castables are a type of castable refractory material composed of corundum or high-alumina clinker, silicon carbide, carbon binders, and various additives. Primarily utilized as the lining for blast furnace tapholes and iron troughs, they are also commonly referred to as “iron trough refractory castables.”

      The high-velocity flow of molten iron and slag—reaching flow rates of several tons per minute—subjects the trough lining to severe mechanical erosion and abrasion. Given this extremely harsh operating environment, the castables are required to possess exceptional resistance to both chemical corrosion and mechanical abrasion. Furthermore, the operation of the iron trough is intermittent; temperatures drop sharply at the conclusion of each tapping cycle, subjecting the castable lining to severe thermal shock. Consequently, materials used for iron trough linings must exhibit excellent thermal shock resistance. The castable must maintain sufficient structural integrity at high temperatures to withstand the erosive forces of the molten iron and slag, as well as its own gravitational load.

      Due to the inherently low permeability of this type of castable, rapid spalling caused by the sudden evaporation of moisture is a significant risk during the drying and baking process. Therefore, anti-explosive agents—such as metallic aluminum powder, aluminum lactate, azodicarbonamide, or anti-explosive fibers—are typically incorporated into the mixture. However, the dosage of these anti-explosive agents must be strictly controlled; excessive addition can lead to a reduction in bulk density and mechanical strength, as well as a deterioration in corrosion and abrasion resistance.

      The specific composition of Al2O3-SiC-C castables varies depending on the specific operating environment and conditions. For instance, castables intended for the iron troughs of large-scale blast furnaces typically require electro-fused corundum as the primary aggregate, whereas medium-to-small blast furnaces may utilize high-alumina clinker as the aggregate material. The proportion of silicon carbide added also varies according to the specific location within the trough: concentrations typically range from 18% to 30% in the taphole and slag-line zones, while areas below the slag line generally contain 12% to 15% silicon carbide.

      Alumina-Silicon Carbide-Carbon castables can be applied either by direct on-site casting or by utilizing pre-cast refractory shapes. The service life of these materials varies significantly, depending largely on the quality of the raw materials employed in their manufacture. In large blast furnaces, corundum-silicon carbide-carbon castables are employed to construct the lining of the main trough (450–500 mm thick); the typical iron throughput before maintenance is 100,000 to 150,000 tons of hot metal, which can be extended to over 300,000 tons following patch-casting or gunning repairs.

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        Thermodynamic Properties of Al2O3-SiC-C Castables

        Al2O3-SiC-C castables have excellent thermal shock resistance and slag resistance, and are widely used in blast furnace tapping channels, ladle linings, and slag lines of mixed iron furnaces. Al2O3-SiC-C (hereinafter referred to as ASC) castables mostly use ultra-low cement bonding systems composed of alumina micropowder, silica micropowder, and a small amount of calcium aluminate cement. Compared with ultra-low cement bonding, calcium aluminate cement bonding without silica micropowder and cement-free bonding have the characteristics of high purity and small amount of liquid phase generated at high temperature. Therefore, it has excellent high-temperature mechanical properties and slag resistance.

        Al2O3-SiC-C Castable Refractory
        Al2O3-SiC-C Castable Refractory

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          Bonding Methods of ASC Castables

          For a long time, people have been accustomed to the ultra-low cement bonding method and the application of silica powder in ASC castables. Therefore, there are few applications and research on calcium aluminate cement bonded ASC castables without silica powder. Common cement-free bonding methods for castables mainly include silica powder agglomeration bonding, hydrated alumina bonding and sol bonding. The shortcomings of silica powder agglomeration bonding are low body strength, hydrated alumina bonding body strength, poor burst resistance, etc., which make these two bonding methods less used in ASC castables. In recent years, with the development of silica sol bonded castable technology, a small amount of silica sol bonded ASC castables have appeared on the market. With the development of alumina sol bonding system, alumina sol bonded ASC castables that replace hydrated alumina may have better performance.

          It is well known that the good thermal conductivity of silicon carbide and carbon in ASC castables gives the material better thermal shock resistance, and the non-wettability of carbon and slag gives the material better slag resistance. Carbon plays a key role in the structure and performance of ASC castables. However, carbon is easily oxidized at high temperatures, which deteriorates the material structure and performance. Carbon can be oxidized by oxygen in the atmosphere and by the material’s own oxide components, such as SiO2. When SiO2 and carbon coexist, the generation and escape of SiO2 gas at high temperatures will consume the carbon in the material, increase the porosity of the material, and thus deteriorate the performance of the material. It can be seen that as far as ASC castables are concerned, the SiO2 component may have an adverse effect on its performance. Based on the above analysis, this work studied the changes in phase composition and chemical composition of four common bonding methods of ASC castables: silica sol, silica-free micropowder cement, hydrated alumina and ultra-low cement, and conducted thermodynamic analysis.

          Rongsheng Al2O3-SIC-C Castable
          Rongsheng Al2O3-SIC-C Castable

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            Thermodynamic Properties of Al2O3-SiC-C Castables

            (1) After calcination at 1350℃, the mass of all samples with different bonding methods increased significantly. Compared with the samples calcined at 1350℃, the mass change rate of the samples calcined at 1500℃ decreased significantly except for the pure calcium aluminate cement bonding method without silica powder.

            (2) Thermodynamic analysis showed that under the carbon coexistence calcination conditions in the Si-O-C-N system, SiO2 is a stable phase when the temperature is below 1431℃, and SiC is a stable phase when the temperature is above 1431℃. Si and SiC in Al2O3-SiC-C castables are oxidized by CO at low temperatures, which increases the C and SiO2 contents in the castables.

            (3) Under the carbon coexistence calcination conditions, the stability order of SiO2-containing compounds is: cristobalite < mullite < anorthite. Under the condition of 1500℃ carbonization, both cristobalite and mullite can be reduced by C, while anorthite can only be reduced by C when there is enough Al2O3 around it. When the temperature does not exceed 1550℃, Si can prevent C from being oxidized by SiO2-containing compounds, and SiC can only prevent C from being oxidized when the temperature is lower than 1431℃.

            (4) When the SiO2 content in the material is high, more SiO gas will escape from the reaction, which will lead to a reduction in sample mass and unstable structure. Considering that silica can promote the formation of SiC, the amount of silica powder added to ASC castables should be minimized.

            Low Cement Silicon Carbide Castable in RS Factory
            Low Cement Silicon Carbide Castable in RS Factory

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              Low Cement SiC Refractory Castable

              Low cement SiC refractory castable is characterized by low linear expansion coefficient, high thermal conductivity, high strength and good wear resistance. It has been applied in thermal equipment such as power generation boilers, non-ferrous metallurgical furnaces and incinerators, and the use effect is good. Low cement SiC refractory castable uses silicon carbide with SiC greater than 97% as refractory aggregate and powder, adds SiO2 ultrafine powder and metal silicon antioxidant, uses CA-70 cement as binder and adds polyphosphate water reducer. The main properties of this material are SiC of 85%, 110℃ drying bulk density, pressure resistance and flexural strength are 2.5g/cm3, 45MPa and 9MPa respectively. After burning at 1000℃, the linear change, pressure resistance and flexural strength are -0.2%, 107MPa and 24MPa respectively. After firing at 1450℃, the linear change, compressive strength and flexural strength are +0.3%, 130MPa and 54MPa respectively, and the thermal conductivity at 400℃ is 12.2W/(m·K).

              Rongsheng Refractory Castable Manufacturer

              Rongsheng Refractory Castable Manufacturer, advanced environmentally friendly fully automatic amorphous refractory production line, specializes in providing refractory products for high-temperature industrial furnace linings. Rongsheng’s refractory products have been sold to more than 120 countries and regions around the world, including South Africa, Chile, Egypt, Colombia, Uzbekistan, Italy, Indonesia, Ukraine, Hungary, Spain, Kenya, Syria, Zambia, Oman, Venezuela, India, Peru, the United States, Ethiopia, Iran, Iraq, Israel, etc. If you need to buy high-quality silicon carbide refractory castables, low-cement silicon carbide refractory castables, Al2O3-SiC-C castables, please contact Rongsheng manufacturers. Get free samples and quotes.

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